C-Hactivation相关论文
A new strategy is developed for the synthesis of 1-aminoisoquinoline derivatives.This Rh(Ⅲ)-catalyzed[4 + 2]annulation ......
We report an unprecedented C-H bond functionalization of cyclopropenes enabled by dinuclear gold catalysis.Highly select......
Following the age of directing group,anchoring catalysis starts coming to the center of the stage.Different from the dir......
A new Rh(Ⅲ)-catalyzed direct C-H alkenylation of 2,3-unsubstitued indoles with alkenyl borates through C-H activation f......
Room-temperature conversion of ethane and the mechanism understanding over single iron atoms confine
The catalytic conversion of ethane to high value-added chemicals is significantly important for utilization of hydrocarb......
Combined C-H Activation/O-H Insertion reaction to Form Tertiary β-Alkoxy Substituted β-Aminophosphat
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Concise Synthesis of 6,7-Disubstituted 3,4-Dihydro-2H-[1,4]diazepino[6,7,1-hi]indol-1-ones as Inhibi
3,4-Dihydro-2H-[1,4]diazepino[6,7,1-hi]-indol-1-ones(Ⅰ)were developed with the aid of protein structure-based drug desi......
Copper-mediated C-H(sp2)/C-H(sp3) coupling of benzoic acid derivatives with ethyl cyanoacetate:an ex
An expedient,copper-mediated,direct C-H(sp2)/C-H(sp3)bond coupling of benzoic acid derivatives with ethyl cyanoacetate b......
Extensive insights into the Mechanism of Single-Electron-Transferin Visible-Light Photoredox Catalys
The visible-light photoredox catalysishas been subject of extensiveexperimental studies,however the detailed mechanism i......
The Activating Effect of Strong Acid for Pd-Catalyzed Directed C-H activation by Concerted Metalatio
A computational study on the orign of the activating effect for Pd-catalyzed directed C-H activation by concerted metala......
C-H Bond Activation and Subsequent C(sp2)-C(sp3) Bond Formation:Coupling of Bromomethyl and Tripheny
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Computational Study on Rh(Ⅲ)-Catalyzed Synthesis of Indolines from Arylnitrones and Alkynes:Origin o
Density functional theory calculations were performed on Rh(Ⅲ)-catalyzed synthesis of indolines from arylnitrones and a......
In recent decades,palladium-catalyzed direct arylation with aryl halides had attracted much attention,however,since 2006......
The possibility to alter the properties of metal complexes by ligand change is without doubt an important driving force ......
Mechanism of Two Successive N-methyl C-H Bond Activations on a Phosphine-Tethered N-Heterocyclic Car
Recently the Cabeza group reported a unique successive N-methyl C–H bond activation on a phosphine-tethered N-heterocyc......
Mechanism and Selectivity of Rh(Ⅲ)-catalyzed Annulation of Enaminones with Alkynes:A Computational S
Rh(Ⅲ)-catalyzed coupling of enaminones with alkynes leading to naphthalene have been investigated by DFT calculations t......
Theoretical Insight into the Pd(Ⅱ)-Catalyzed Coupling Reaction of Toluene with Phenylglycine Azlacto
Computational studies have been applied to gain insight into the mechanism of Pd(Ⅱ)catalyzed oxidative coupling of tolu......
Water-Medium C-H Activation over a Hydrophobic Perfluoroalkane-Decorated Metal-Organic Framework Pla
Direct construction of C-C bond from inert C-H bond is a highly efficient and sustainable strategy in synthesis of aryla......
Synthesis of Polysubstituted Furans via Copper-Mediated Annulation of Alkyl Ketones with α,β-Unsatur
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Phosphorus-containing compoundsplay important roles in many areasincludingorganometallic catalysis,organocatalysis,agro-......
The discovery of novel synthetic methods that allowed rapid construction of hard-to-access seven-or eight-membered carbo......
Cytochrome P450 monooxygenase are synthetically useful enzymes and promising versatile oxidative biocatalysts,which cata......
Aryl nitriles are important structural motifs present in various therapeutically significant natural products and market......
Cooperation of SET and CMD mechanisms of cobalt-catalyzed dual C-H activation and cross-coupling rea
Almost all the Co-catalyzed C - H functionalizations have been achieved based on either single electron transfer(SET)or ......
Rhodium(Ⅲ)-Catalyzed C-H Activation and Annulation with 1-Alkynylphosphine Sulfides:Regioselective S
Phosphine-containing motifs have been playing an indispensable role in synthetic chemistry,so it is quite important to d......
Tunable Cascade Reactions of Alkynols with Alkynes Using a Combination of Sc(OTf)3 and Rhodium Catal
Transition metal-catalyzed cascade transformations of alkynols have recently attracted extensive interest because they a......
Metallalkenyl,Metallacyclopropene,or Metallallylcarbenoid:Ru-Catalyzed Annulation between Benzoic Ac
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Mechanism and Origin of Stereoselectivity of Pd-Catalyzed Cascade Annulation of Aryl Halide,Alkene,a
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Design,synthesis of2-methyl-7-aminobenzoxazole as auxiliary in the Pd(Ⅱ)-catalyzed arylation of β-po
In recent years,transition metal-catalyzed functionalization of C-H bond has emerged as an efficient method for C-C and ......
Copper-catalyzed Cascade Cycloamination and Acyloxylation: Synthesis of Multisubtituted 4-Acyloxy-1H
Transition-metal-catalyzed selective C-O bond formation via C-H functionalization has been developed as an efficient met......
Construction of Organic Optoelectronic Molecules Based on Highly Efficient and Selective C-H Bond Tr
The design and synthesis of π-conjugated organic molecules are one of the most important research contents of organic c......
Catalytic Transformations of Phenol-derived Biaryls by using a Cooperative C-H Activation/Dearomatiz
Transition metal catalysis has proven to be a fascinating platform to forge more efficient and economical tools for the ......
Three-Component Synthesis of 2-Heteroaryl-3-hydroxybenzo[b]-thiophenes under Transition-Metal-Free C
Main observation and conclusionrnA convenient synthetic route to 2-heteroaryl-3-hydroxybenzo[b]thiophene derivatives via......
N-苯氧基乙酰胺是铑(Ⅲ)催化无外加氧化剂条件下碳氢活化反应中的一类典型底物.为了研究这类分子中O-NHAc部分作为氧化导向基团的......
Main observation and conclusionrn[Cp*Co(CO)l2] effectively catalyzes pyridyl-directed C-H allylation of arenes with ally......
Transition-metal mediated activation of inert chemical bonds is an ongoing topic in homogeneous catalysis.In view of the......
Substituted benzothiazole derivatives are a class of important compounds in organic synthesis and pharmaceutical int......
Ortho-Mono-Alkynylation and Alkenylation of 7-Azaindoles and the Cascade Synthesis of 7-Azaindole Fu
The 7-azaindole skeletone is prevalent in commercial drugs and biologically active compounds,1 however,the direct mo......
Rhodium-Catalyzed Annulation of Tertiary Aniline N-Oxides to N-AlkylindolesRegioselective C-H Activa
Despite the fact that the direct C-H transformation of various compounds has been established,tertiary anilines rema......
C-N bond formation reaction plays an important role in organic synthesis,which is often used in the synthesis of nat......
Organic reactions that involve transition metal-catalyzed direct functionalization of non-activated C(sp2)-H bonds r......
Carboxylic Acid as Traceless Directing Group for PdCu-Catalyzed Decarboxylative ortho-halogenation o
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Over the last two decades,the use of metal-mediated direct C-H functionalization has grown rapidly as it enables the......
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Benzoisothiazoles are ubiquitous structural motifs found in agrochemicals and pharmaceuticals.1 To date,considerable......
Rh(I)-Catalyzed Redox-Economic Cross Coupling of Carboxylic Acids with Arene Directed by N-contained
A new concept to carry out the pseudo oxidative decarboxylative coupli ng of carboxylic acids and arenes in the abse......
